Mirrors have been used in outdoor design for at least two centuries - Humphry Repton wrote about their use. The old mirrors have not survived because the silvering process was not weather-resistent. Modern mirror-coatings are much tougher and alternatives to glass mirrors are available:
Garden mirrors bring light into dark corners and can increase the apparent extent of a space.
over 5 years by Anonymous 5 / 5I found an internet company doing mirrors from polished stainless, www.metalmental.co.uk
almost 6 years by Anonymous 5 / 5Your acrylic mirrors aren't big enough for use in the garden. I'd be looking for something like 32"W x 48"L.
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Water on mirrored steel
Reflections on mirrored stone
Mirrors create the illusion of a window into another garden